The following is a list prepared by the chapter of all the known/identified past presidents of the K. M. Van Zandt Chapter.
| President | Term | |
|---|---|---|
| Elmer Renfro | 1932 | Deceased |
| Frederick C. Cutter | 1939 | Deceased |
| Cornelius B. Savage | 1946 | Deceased |
| Robert Garnett Waggener | 1947-1948 | Deceased |
| John Webster Naylor, Sr. | 1949 | Deceased |
| Chalmers W. Hutchinson | 1950 | Deceased |
| Harold G. Neely | 1951 | Deceased |
| Robb R. Stegall | 1952 | Deceased |
| William D. Cecil | 1953 | |
| Dr. W. C. Nunn | 1954 | Deceased |
| W. C. Preston, Jr. | 1955 | |
| Marvin C. Nichols | 1956 | Deceased |
| Joseph P. Gudger | 1957 | Deceased |
| Col. Uel Stephens, Jr. | 1957 | Deceased |
| Lorin Boswell | 1958 | Deceased |
| Elton M. Hyder, Sr. | 1959 | Deceased |
| Wray D. Brown | 1960-1961 | Deceased |
| R. Wright Armstrong | 1962 | Deceased |
| Dr. J. Franklin Campbell | 1963 | Deceased |
| Bill Hutcheson | 1963 | Deceased |
| Hubert J. Foster, Jr. | 1964 | Deceased |
| Dr. John D. Pumphrey, M.D. | 1965-1966 | Deceased |
| Christopher Larkin | 1967 | Deceased |
| Col. Karl E. Wallace, Sr. | 1968-1969 | Deceased |
| William Lewis Love | 1970 | Deceased |
| George C. Thompson, Jr. | 1971 | Deceased |
| Brig. Gen. Lynn M. Yeatts | 1972 | Deceased |
| Col. Stanton C. Parker | 1972 | Deceased |
| Sam Woody Acola | 1973-1974 | Deceased |
| Col. J. L. Sibley Jennings | 1974-1975 | Deceased |
| George C. Thompson, Jr. | 1976-1977 | Deceased |
| Kenneth R. Cox | 1977-1978 | |
| William H. Thompson | 1978-1980 | Deceased |
| Warren C. Russell | 1981 | |
| James R. Herman, Jr. | 1982-1983 | Deceased |
| Rev. C. Rogers McLane | 1984 | Deceased |
| Hugh D. McKay, Jr. | 1985 | Deceased |
| George W. Demeritt | 1986 | Deceased |
| Harold R. Bost | 1987-1988 | Deceased |
| Hugh D. McKay, Jr. | 1989 | Deceased |
| Robert Holloway | 1990 | |
| James M. Head, Jr. | 1991 | Deceased |
| W. Scott Manning, Jr., D.V.M. | 1992-1993 | |
| Henry S. Ball | 1994-1995 | Deceased |
| Robert M. Daley | 1995 | |
| Donald G. Pray | 1996 | Deceased |
| Edward P. Maddox, III, D.V.M. | 1997-1998 | Deceased |
| Robert R. Truitt, Sr. | 1999-2001 | Deceased |
| James E. Alderman | 2001-2003 | |
| Donald P. Goodman, PHD | 2003-2005 | Deceased |
| James E. Haynes | 2005-2007 | |
| Gene Shields | 2007-2008 | Deceased |
| Thomas C. McMurray | 2008-2009 | Deceased |
| Robert R. Truitt, Sr. | 2009-2010 | Deceased |
| L. Vaughn Oliver | 2010-2011 | |
| Raymond L. Leftwich | 2012-2013 | |
| Russell W. Leavens | 2014-2015 | Deceased |
| Lawrence M. Connelley | 2016-2017 | |
| Gerald A. Gieger | 2018-2019 | |
| Ronald J. Turner | 2020-2021 | |
| Robert G. Gresham | 2022-2023 | |
| Ronald J. Turner | 2024- |
